Organic amine salts are versatile ionic materials used to introduce organic cations and counterions into advanced energy and optoelectronic systems. In halide perovskite research, they can serve as primary precursor components, dimensional-control agents, interfacial modifiers, crystallization additives, or surface-passivation materials, depending on the cation structure and selected anion.
Eata Energy supports material developers with a focused range of organic ammonium halides and related amine salts for formulation, thin-film processing, crystal growth, and device-oriented research.
The behavior of an organic amine salt is governed by more than its basic chemical identity. Molecular size, charge density, aromaticity, chain length, functional groups, and the halide counterion can influence solubility, lattice interaction, film morphology, interfacial energy, and the formation of three-dimensional or layered structures. This makes organic ammonium salts especially useful when researchers need a controllable route to tune hybrid materials without changing the entire processing platform.
Figure 1. High-purity organic amine salt crystals prepared for advanced materials development.
The following examples illustrate frequently requested product types used across perovskite photovoltaics, light-emitting devices, photodetectors, low-dimensional semiconductors, and related materials research. Final suitability depends on the complete device stack and formulation conditions.
| Representative Material | Formula | Counterion | Typical Research Role |
| Methylammonium iodide (MAI) | CH3NH3I | Iodide | 3D perovskite precursor; composition and film-development studies |
| Methylammonium bromide (MABr) | CH3NH3Br | Bromide | Bandgap and halide-composition adjustment; bromide perovskites |
| Formamidinium iodide (FAI) | HC(NH2)2I | Iodide | Formamidinium-based perovskite absorbers and mixed-cation formulations |
| Formamidinium bromide (FABr) | HC(NH2)2Br | Bromide | Wide-bandgap and mixed-halide precursor systems |
| Phenethylammonium iodide (PEAI) | C8H12IN | Iodide | Surface treatment; 2D or quasi-2D perovskite formation |
| Phenethylammonium bromide (PEABr) | C8H12BrN | Bromide | Layered bromide materials; interface and emission-layer engineering |
| n-Butylammonium iodide (BAI) | C4H12IN | Iodide | Ruddlesden-Popper spacer cation and dimensional control |
| n-Butylammonium bromide (BABr) | C4H12BrN | Bromide | Quasi-2D bromide perovskites and optoelectronic formulations |
| Benzylammonium iodide (BzAI) | C7H10IN | Iodide | Aromatic spacer cation; layered hybrid materials |
| Hexylammonium iodide (HAI) | C6H16IN | Iodide | Long-chain spacer cation for 2D hybrid structures |
| Guanidinium iodide (GAI) | CH6IN3 | Iodide | Cation-alloying and lattice-interaction studies |
| Ethylenediammonium diiodide (EDAI2) | C2H10I2N2 | Diiodide | Diammonium passivation and Dion-Jacobson-type materials |
Figure 2. Ionic building blocks and counterions represented within an organic amine salt lattice.
Small organic cations such as methylammonium and formamidinium are widely used to construct or modify the A-site composition of hybrid metal-halide perovskites. Their iodide, bromide, and chloride salts allow researchers to adjust cation ratios and halide content while developing absorber layers for solar cells, tandem architectures, LEDs, detectors, and other thin-film devices.
Bulky monoammonium and diammonium salts can separate inorganic metal-halide sheets and promote layered structures. Phenethylammonium, butylammonium, benzylammonium, hexylammonium, and diammonium cations are frequently investigated as spacer species. By changing the spacer length, aromatic group, substitution pattern, or charge functionality, researchers can study orientation, dielectric confinement, moisture tolerance, excitonic behavior, and charge transport.
Figure 3. Organic spacer cations separating inorganic sheets in a low-dimensional hybrid perovskite.
Organic ammonium halides are also used as post-treatment reagents or formulation additives. Depending on the chemistry and processing conditions, they may interact with under-coordinated surface sites, influence halide balance, modify grain boundaries, or generate a thin low-dimensional phase at an interface. These effects can be investigated to reduce non-radiative recombination, improve photoluminescence, tune interfacial energetics, or stabilize film morphology.
Figure 4. Organic ammonium species distributed across a perovskite surface and grain interface.
In light-emitting and nanocrystal systems, the organic cation can affect phase distribution, crystal dimensions, ligand environment, emission color, and defect density. Aromatic, fluorinated, and long-chain amine salts are often screened when developing quasi-2D emission layers or surface-modified nanomaterials. Similar materials may also be evaluated in photodetectors, X-ray detection research, and other hybrid semiconductor platforms.
Organic amine salts can be incorporated into one-step and sequential solution deposition, antisolvent processing, blade coating, slot-die coating, ink formulation, crystal growth, or multi-source vacuum deposition studies. The appropriate material grade, water content, solution concentration, and storage approach should be selected around the sensitivity of the target process.
Figure 5. Precursor solution preparation and coated-substrate development for thin-film research.
| Selection Factor | Questions to Consider | Why It Matters |
| Cation structure | Small A-site cation, bulky spacer, aromatic cation, long-chain cation, or diammonium ion? | Controls lattice compatibility, dimensionality, packing, and interfacial interaction. |
| Counterion | Iodide, bromide, chloride, or mixed-halide strategy? | Influences precursor stoichiometry, phase chemistry, bandgap, and processing behavior. |
| Purity profile | What assay, trace-metal, residual-solvent, or moisture limits are required? | Impurities can alter nucleation, recombination, color, and reproducibility. |
| Solvent compatibility | Will the salt be used in DMF, DMSO, alcohols, water, or another medium? | Solubility and solution stability affect concentration accuracy and film uniformity. |
| Process route | Bulk precursor, additive, surface treatment, crystal growth, or vapor deposition? | The intended step determines concentration range, packaging, and handling needs. |
| Scale and packaging | Screening quantity, pilot quantity, or application-specific pack size? | Matching pack format to use conditions helps protect quality during repeated handling. |
Some energy-material programs require a cation structure, counterion, purity profile, concentration, solvent format, or packaging configuration that is not covered by a standard item. Eata Energy can discuss custom organic amine salt development, purification, anion selection, solution preparation, and project-specific packaging based on the target chemistry and technical feasibility.
To request a quotation, share the material name or molecular structure, desired counterion, target purity, quantity, analytical requirements, preferred form, and intended application. This information helps define a practical specification for your evaluation program.
| Catalog Number | Product Name | Order | Quantity |
|---|---|---|---|
| SDPOAS-0001 | 98% 3-(Methylthio)propylammonium Bromide | Inquiry | |
| SDPOAS-0002 | 98% 2-(Piperazin-1-yl)ethylamine Hydroiodide | Inquiry | |
| SDPOAS-0003 | 98% (R)-1-(4-Methylphenyl)ethylammonium Iodide | Inquiry | |
| SDPOAS-0004 | 98% Propylphosphonic Acid 3-Ammonium Bromide | Inquiry | |
| SDPOAS-0005 | 98% 2-(Methylthio)ethylammonium Iodide | Inquiry | |
| SDPOAS-0006 | 98% Tetrahydrofuran-3-ylmethylammonium Iodide | Inquiry | |
| SDPOAS-0007 | 4-(Trifluoromethyl)benzamidine Hydrobromide | Inquiry | |
| SDPOAS-0008 | 1-(4-Methoxyphenyl)ethylammonium Iodide | Inquiry | |
| SDPOAS-0009 | 2-Methoxyethylamine Hydrobromide | Inquiry | |
| SDPOAS-0010 | 4-Fluorobenzamidine Hydrobromide | Inquiry |
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